posted 19 Feb 2017, 06:04 by Scott Melville
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updated 19 Feb 2017, 06:06
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The second law of thermodynamics from symmetry and unitarity
(30 pages)
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Integrating out the fast degrees of freedom in a quantum many-body system leaves us with an effective field theory of a (typically) non-equilibrium configuration of slow degrees of freedom. Using this EFT, a local form of the second law is derived: that in local equilibrium, the entropy production at each spacetime point is positive semidefinite. Interestingly, the analogue of the detailed balance condition seems to be the presence of a symmetry in the classical limit, in this case Z2, which defines an entropy current. The sign of the divergence of this current is determined by unitarity in the quantum theory.
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The relation between unitarity violation and entropy generation is an interesting one, which is becoming increasingly well-understood via non-equilibrium formulations of QFT. It suggests that in future, we may be able to make sense of a unitarity breakdown (say at high energies) in terms of some non-adiabatic process.
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